Browsing by Subject "Organic solvents"
Now showing items 1-11 of 11
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Article
Biosourced amphiphilic degradable elastomers of poly(glycerol sebacate): Synthesis and network and oligomer characterization
(2013)Glycerol (G, a triol) and sebacic acid (S, an α,ω-dicarboxylic acid) were condensed in the bulk to obtain poly(glycerol sebacate) (PGS) cross-linked elastomers which were characterized in terms of their swelling, thermal, ...
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Article
Degradable amphiphilic end-linked conetworks with aqueous degradation rates determined by polymer topology
(2009)Degradable amphiphilic conetworks, based on end-linked amphiphilic ABA triblock copolymers with a labile fragment in the middle, were synthesized by sequential group transfer polymerization (GTP) of monomers and cross-linker, ...
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Article
Dissecting the stabilization of iodide at the air-water interface into components: A free energy analysis
(2006)Recent experiments and simulations show that large chaotropic anions favor solvation at the water surface, mainly due to induction interactions dominated by ionic polarizabilities. We compare the solvation free-energy ...
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Article
Flexible lanthanide MOFs as highly selective and reusable liquid MeOH sorbents
(2013)A series of new 3-D Ln3+ metal-organic frameworks (MOFs), which are based on the semi-rigid ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], [Ln2(CIP) 2(DMF)4-x(H2O)x] (Ln3+ = La3+, Ce3+, Pr3+, Sm3+, ...
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Conference Object
Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid
(2007)Two series of model amphiphilic polymer conetworks were synthesized by group transfer polymerization (GTP). The first one contained methyl methacrylate (MMA) and the second one 2-butyl-l-octyl methacrylate (BOMA) as ...
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Article
The production and decay kinetics of CIOO in water and freon-11: A time-resolved resonance Raman study
(2001)The production and decay kinetics of ClOO in water and freon-11 were studied using time-resolved resonance Raman (TRRR) spectroscopy. The formation of ClOO following OClO photoexcitation at 390 nm was investigated using ...
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Article
Simplified alpha-spectroscopic analysis of uranium in natural waters after its separation by cation-exchange
(2010)A relatively rapid, economic and robust procedure is described for the alpha-radiometric analysis of natural waters. The analysis is performed by alpha-spectroscopy after pre-concentration and separation of uranium by ...
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Article
Synthesis and characterization of amphiphilic diblock copolymers of 2-(1-imidazolyl)ethyl methacrylate and styrene
(2014)Six amphiphilic diblock copolymers based on the hydrophilic monomer 2-(1-imidazolyl)ethyl methacrylate (ImEMA) and the hydrophobic monomer styrene (Sty) were prepared by sequential reversible addition-fragmentation chain ...
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Article
Synthesis and characterization of reversible and self-healable networks based on acylhydrazone groups
(2014)A series of seven dynamic covalent networks based on pentaerythritol tetra(benzohydrazide) and 1,10-decanediol dibenzaldehyde were prepared in N,N-dimethylformamide (DMF). The equilibrium degree of swelling in DMF and the ...
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Article
Synthesis, characterization, and modeling of double-hydrophobic model networks based on cross-linked star copolymers of n-butyl methacrylate and methyl methacrylate
(2006)Seven model networks of a new structure, that of cross-linked "in-out"\star polymers, were synthesized by the group transfer polymerization of the Hydrophobic monomers methyl methacrylate (MMA) and n-butyl methacrylate ...
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Article
Well-defined diblock copolymers possessing fluorescent and metal chelating functionalities as novel macromolecular sensors for amines and metal ions
(2012)The amino- and metal-ion sensing capability of a novel type of well-defined block copolymers based on 9-anthrylmethyl methacrylate (AnMMA